The influence of transition metals on the electronic structure of ZnSe host crystal: fundamental reflectivity analysis

The optical properties of the semiconducting compounds Zn1-xMexSe (Me = Ti, V, Cr, Mn, Fe, Co, and Ni) crystallizing in the zinc-blende structure have been investigated. Reflectivity spectra of these materials have been taken at room and liquid nitrogen temperatures. The measurements have been performed in the 4-25 eV energy range using synchrotron radiation from the ADONE storage ring in Frascati. Comparisons between the reflectivity spectra of the ternary systems and those of the host crystal ZnSe have been made, and models explaining the influence of the transition metal ions on the electronic structure of the host crystal ZnSe have been discussed