Synthesis and characterization of a new Benzofulvene polymer showing self-assembling and thermal-induced disassembling properties

A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents and thermoreversible polymerization properties. An interesting application of the polymer in synthesis is reported.