Radiationless decay in the region of the 2t(2g) and 4e(g) resonances in SF(6)

The S 2p Auger spectrum of SF6 has been studied in the region of the 2t2g and 4eg resonances. The partial Auger spectra due to the ionization of the 2p spin-orbit components and of a shake-up satellite state have been measured selectively by tuning the photon energy and using the Auger electron-photoelectron coincidence technique. A detailed analysis of the Auger spectrum has also been performed using the Green's function-based second-order algebraic diagrammatic construction method.