Molecular beam studies of ammonia clustered with metals produced by pulsed laser reactive ablation

The results of spectroscopic studies of Me(NH3)n clusters formed in the reaction of photoablated III group metal vapor with gaseous ammonia are reported here. The photoionization spectra of Me(NH3) clusters exhibit some features attributed to vibronic excitation of ionic clusters and transitions to autoionizing neutral Rydberg states. The first ionization potentials of these metals clustered with more than one ammonia molecule appear to decrease almost monotonically with increasing clusters size. The observed trend is consistent with a model in which the unpaired valence electron of the ground electronic state is delocalized in a well bound surface state. The data are confirmed by energetics and structure calculations performed by density functional method.