Silicene on Ag(111): A honeycomb lattice without Dirac bands

The discovery of (4×4) silicene formation on Ag(111) raised the question whether silicene maintains its Dirac fermion character, similar to graphene, on a supporting substrate. Previous photoemission studies indicated that the ? band forms Dirac cones near the Fermi energy, while theoretical investigations found it shifted at deeper binding energy. By means of angle-resolved photoemission spectroscopy and density-functional theory calculations we show instead that the ?-symmetry states lose their local character and the Dirac cone fades out. The formation of an interface state of free-electron-like Ag origin is found to account for spectral features that were theoretically and experimentally attributed to silicene bands of ? character.