Temperature dependence of the rigid amorphous fraction of poly(butylene succinate)

In this contribution the temperature evolution of the constrained or rigid amorphous fraction (RAF) of biodegradable and biocompatible poly(butylene succinate) (PBS) was quantified, after detailed thermodynamic characterization by differential scanning calorimetry and X-ray diffraction analysis. At the glass transition temperature, around -40 °C, the rigid amorphous fraction in PBS is about 0.25. It decreases with increasing temperature and becomes zero in proximity of 25 °C. Thus, at room temperature and at the human body temperature, all the amorphous fraction is mobile. This information is important for the development of PBS products for various applications, including biomedical applications, since physical properties of the rigid amorphous fraction, for example mechanical and permeability properties, are different from those of the mobile amorphous fraction.