Cathodic C- H electro-activation in ionic liquid: An improved electrochemical method for the conjugate addition of 1,3-dicarbonyl compounds
Articolo
Data di Pubblicazione:
2008
Abstract:
The constant current electrolysis of 1,3-dicarbonyl compounds in 1-ethyl-3-methylimidazolium ethylsulfate (EMIMEtSO4) ionic liquid provided the direct deprotonation of the methylene active functionality to the cathode: the corresponding enolates efficiently underwent to the one-pot Michael addition with activated olefins.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
Ionic liquid; electrochemical method; conjugate addition
Elenco autori:
Villano, Rosaria
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