Permian hydrothermal alteration preserved in polymetamorphic basement and constraint for ore-genesis (Alpi apuane, italy)

The reconstruction of the polymetamorphic history of basement rocks in orogens is crucial for deciphering past geodynamic evolution. However, the current petrographic features are usually interpreted as the results of the metamorphic recrystallization of primary sedimentary and/or magmatic features. In contrast, metamorphic rocks derived by protoliths affected by premetamorphic hydrothermal alterations are rarely recognized. This work reports textural, mineralogical and geochemical data of metasedimentary and metaigneous rocks from the Paleozoic succession of the Sant'Anna tectonic window (Alpi Apuane, Tuscany, Italy). These rocks were recrystallized and reworked during the Alpine tectono-metamorphic event, but the bulk composition and some refractory minerals (e.g., tourmaline) are largely preserved. Our data show that the Paleozoic rocks from the Alpi Apuane were locally altered by hydrothermal fluids prior to Alpine metamorphism, and that the Permian magmatic cycle was likely responsible for this hydrothermal alteration. Finally, the Ishikawa Alteration Index, initially developed for magmatic rocks, was applied to metasedimentary rocks, providing a useful geochemical tool for unravelling the hydrothermal history of Paleozoic rocks, as well as a potential guide to the localization of hidden ore deposits in metamorphic terranes.