Ligand-free gold atom clusters adsorbed on graphene nano sheets generated by oxidative laser fragmentation in water

Over three decades after the first synthesis of stabilized Au-55-clusters many scientific questions about gold cluster properties are still unsolved and ligand-free colloidal clusters are difficult to fabricate. Here we present a novel route to produce ultra-small gold particles by using a green technique, the laser ablation and fragmentation in water, without using reductive or stabilizing agents at any step of the synthesis. For fabrication only a pulsed laser, a gold-target, pure water, sodium hydroxide and hydrogen peroxide are deployed. The particles are exemplarily hybridized to graphene supports showing that these carbon-free colloidal clusters might serve as versatile building blocks. (C) 2014 Elsevier B.V. All rights reserved.