Structural and chemical study of weishanite, (Au,Ag,Hg), from the Keystone mine, Colorado, USA

Structural data for weishanite, an alloy of Au, Ag and Hg, were collected for the first time from a crystal from the Keystone Mine, Colorado, USA. The structure was solved in the space group P63/mmc with the unit cell a = 2.9348(8) and c = 4.8215(18) Å] and refined to R = 0.0299 for 40 observed reflections [4?(F) level] and four parameters and to R = 0.0356 for all 47 independent reflections. The weishanite structure can be considered a derivative of the zinc structure, with Au, Ag and Hg disordered in the same structural position. On this basis, we suggest that the formula is normalized to 1 atom with Z = 2, leading, for the sample investigated, to Au0.41Ag0.31Hg0.28 (electron microprobe data). Accordingly, weishanite can be considered the Au-rich isotype of schachnerite. A comparison with other Au/Ag-Hg alloys is presented together with a critical discussion about the nomenclature rules to be applied to alloys and simple metals