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Electrodeposition studies in the MnO2 + PbO2 system: formation of Pb3Mn7O15

Articolo
Data di Pubblicazione:
2000
Abstract:
The anodic codeposition of PbO2 and MnO2 was investigated. Simultaneous oxidation of Mn2+ and Pb2+ ions in an acetate bath yielded deposits containing crystalline MnO2 and PbO2, and probably a ternary amorphous phase. Deposits with a ratio Pn/Mn = 3/7 were easily obtained at T>50 °C, but no crystalline Pb3Mn7O15 or other mixed oxides formed in the as-deposited material. Oxide mixtures could be quantitatively converted to Pb3Mn7O15 by annealing at 800 °C.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
Acetate; Anodic codeposition; Lead oxide; Manganese oxide; Mixed oxides
Elenco autori:
Guerriero, Paolo; Musiani, Marco; Cattarin, Sandro
Link alla scheda completa:
https://iris.cnr.it/handle/20.500.14243/172025
Pubblicato in:
JOURNAL OF APPLIED ELECTROCHEMISTRY
Journal
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URL

http://link.springer.com/article/10.1023%2FA%3A1003863720693
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