Growth assessment of (002)-oriented AN thin films on Ti bottom electrode deposited on silicon and kapton substrates

In the present work, the sputtering deposition conditions allowing the achievement of (002)-oriented aluminum nitride (AIN) thin films on titanium (Ti) bottom electrode were assessed on both silicon and kapton substrates. The AIN grain orientation was enhanced by tuning the conditions used for the Ti deposition, particularly the radiofrequency (RF) power applied to Ti target and the total pressure in the deposition chamber. Sputtered species energy and their flux towards the substrate were identified as key parameters to interpret Ti structure and morphology on both substrates, and to understand how they drive the AIN crystallization process. The evolution of morphology and structure of single Ti films and of the A1N/Ti system was characterized by X-ray Diffraction, Scanning Electron Microscopy and Transmission Electron Microscopy. Highly oriented AIN films were obtained on both substrates when the underneath Ti layer was mainly (002)-oriented; the presence in the Ti films of grains with (100) orientation produced a degree of misorientation in the following AIN growth, also resulting in a significant change of the surface morphology, on both substrates. The successful deposition of A1N/Ti on kapton substrate represents a promising result for the integration of this material in flexible piezoelectric electronics. (C) 2017 Elsevier Ltd. All rights reserved.