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Cauchy relation in relaxing liquids

Articolo
Data di Pubblicazione:
2008
Abstract:
The Cauchy-like relation M-infinity=A+BG(infinity) has recently been found to hold for the high frequency limit values of the longitudinal modulus M-infinity and transverse modulus G(infinity) of viscoelastic liquids, with B similar or equal to 3 in all the investigated systems. The Brillouin scattering results here reported for curing epoxy systems and thermal glass formers give evidence for the validity of a Cauchy-like relation M-'=A+BG(') for the real part of the elastic moduli measured at finite frequencies. Our results suggest as well the validity of a pure Cauchy relation Delta M=3 Delta G for the relaxation strengths of longitudinal and shear moduli in relaxing liquids. (c) 2008 American Institute of Physics.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
RAYLEIGH-BRILLOUIN-SCATTERING; SUPERCOOLED LIQUID; LIGHT-SCATTERING; SALOL; DYNAMICS
Elenco autori:
Caponi, Silvia
Autori di Ateneo:
CAPONI SILVIA
Link alla scheda completa:
https://iris.cnr.it/handle/20.500.14243/457769
Pubblicato in:
THE JOURNAL OF CHEMICAL PHYSICS
Journal
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