Data di Pubblicazione:
2008
Abstract:
Relaxation in glass-forming substances is necessarily a many-body problem because of intermolecular interactions and constraints. Results from molecular dynamics simulations and experiments are used to reveal the critical elements and general effects originating from many-body relaxation, but not dealt with in conventional theories of the glass transition. Although many-body relaxation is still an unsolved problem in statistical mechanics, these critical elements and general effects will serve as guides to the construction of a satisfactory theory of the glass transition. This effort is aided by concepts drawn from the coupling model, whose predictions have been shown to be consistent with experimental facts.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
MOLECULAR-DYNAMICS SIMULATION; MISCIBLE POLYMER BLENDS; DEPOLARIZED LIGHT-SCATTERING; GOLDSTEIN BETA-RELAXATION; MOLTEN ZINC-CHLORIDE
Elenco autori:
Prevosto, Daniele; Capaccioli, Simone
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