Isomerization of allylic alcohols to carbonyl compounds by aqueous-biphasic rhodium catalysis

Articolo
Data di Pubblicazione:
2001
Abstract:
Isomerization of allylic and homoallylic alcohols is catalyzed by the zwitterionic Rh(I) complex (sulphos)Rh(cod) in water-n-octane to give the corresponding aldehyde or ketone in high yields and chemoselectivity. A metal hydride mechanism is proposed on the basis of various independent experiments in both homogeneous and biphasic systems [sulphos=-O3S(C6H4)CH2C(CH2PPh2)3
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
rodio; catalisi bifasica; meccanismo; alcol allilici; aldeidi
Elenco autori:
Autori di Ateneo:
Link alla scheda completa:
https://iris.cnr.it/handle/20.500.14243/170088
Pubblicato in:
NEW JOURNAL OF CHEMISTRY (1987)
Journal