Evolution of fluid geochemistry at the Turrialba volcano (Costa Rica) from 1998 to 2008

Turrialba (10°02?N, 83°45?W) is a 3,349-m high stratovolcano belonging to the Holocene "Cordillera Central" volcanic belt of Costa Rica. The summit consists of three EW-oriented craters (East, Central, and West). Since its last eruptive phase (1864-1866), the Central and West craters have displayed modest fumarolic activity, with outlet temperatures clustering around 90°C. In 2001, seismic swarms, ground deformation, and increasing fumarolic activity occurred. From 2005 to 2008, new fumarolic vents opened between and within the Central and West craters, and along the western and southwestern outer flanks of the volcanic edifice. These physical changes were accompanied by a drastic modification in the gas chemistry that can be divided in three stages: (1) hydrothermal (from 1998 to autumn 2001), characterized by the presence of H2O, CO2, H2S, and, to a very minor extent, HCl and HF; (2) hydrothermal/magmatic (autumn 2001- 2007), with the appearance of SO2 and a significant increase of HCl and HF; and (3) magmatic-dominated (2007-2008), characterized by increased SO2 content, SO2/ H2S>100, and temperatures up to 282°C. Accordingly, gas equilibrium in the CO2-CH4-H2 system suggests a progressive evolution of the deep fluid reservoir toward higher temperatures and more oxidizing conditions. The chemical- physical modifications of Turrialba in the last decade can be interpreted as part of a cyclic mechanism controlling the balance between the hydrothermal and the magmatic systems. Nevertheless, the risk of rejuvenation of the volcanic activity cannot be excluded, and an appropriate seismic, ground deformation, and geochemical monitoring program is highly recommended. Turrialba lies at a distance of 35 and 15 km from San José and Cartago, respectively, the two largest cities in Costa Rica.