Data di Pubblicazione:
2009
Abstract:
By combining the results of kinetic measurements with DFT
calculations we provide a clear-cut evidence of the merging
between the E2 and E1cb reaction mechanisms for a large
series of leaving groups. Our results solve a long-debated
issue in chemical reactivity with profound implications both from a fundamental and biological point of view, thus paving
the way to further investigations with different substrates.
calculations we provide a clear-cut evidence of the merging
between the E2 and E1cb reaction mechanisms for a large
series of leaving groups. Our results solve a long-debated
issue in chemical reactivity with profound implications both from a fundamental and biological point of view, thus paving
the way to further investigations with different substrates.
Tipologia CRIS:
01.01 Articolo in rivista
Elenco autori:
Tarantelli, Francesco; Mosconi, Edoardo; DE ANGELIS, Filippo; Belpassi, Leonardo
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