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Configurational entropy of hard spheres

Articolo
Data di Pubblicazione:
2007
Abstract:
We numerically calculate the configurational entropy S-conf of a binary mixture of hard spheres, by using a perturbed Hamiltonian method trapping the system inside a given state, which requires fewer assumptions than the previous methods (Speedy 1998 Mol. Phys. 95 169). We find that Sconf is a decreasing function of the packing fraction. and extrapolates to zero at the Kauzmann packing fraction phi K similar or equal to 0.62, suggesting the possibility of an ideal glass transition for the hard-sphere system. Finally, the Adam-Gibbs relation is found to hold.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
GLASS-FORMING LIQUIDS; SUPERCOOLED LIQUIDS; ENERGY LANDSCAPE; BINARY-MIXTURE; TRANSITION
Elenco autori:
Angelani, Luca
Autori di Ateneo:
ANGELANI LUCA
Link alla scheda completa:
https://iris.cnr.it/handle/20.500.14243/167532
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