Data di Pubblicazione:
2009
Abstract:
We present an experimental setup to study terahertz dynamics in fluids under high pressure,
employing inelastic x-ray scattering and diamond anvil cell techniques. The use of a carefully
designed vacuum chamber and the minimization and control of sources of parasitic scattering
allowed circumventing previous limitations due to important empty cell contributions to the
scattering signal. The successful implementation of our setup is demonstrated in the case of
supercritical fluid argon, for which a full viscoelastic analysis yields the dispersion relation of sound
waves, the generalized heat capacity ratio, and longitudinal viscosity. Our results are in excellent
agreement with available experimental observables and molecular dynamics simulations.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
high pressure physics; synchrotron inelastic x-ray scattering
Elenco autori:
Ruocco, Giancarlo; Santoro, Mario; Scopigno, Tullio; Gorelli, FEDERICO AIACE
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