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Dynamics of uniaxial hard ellipsoids

Academic Article
Publication Date:
2007
abstract:
We study the dynamics of monodisperse hard ellipsoids via a new event-driven molecular dynamics algorithm as a function of volume fraction phi and aspect ratio X-0. We evaluate the translational D-trans and the rotational D-rot diffusion coefficients and the associated isodiffusivity lines in the phi-X-0 plane. We observe a decoupling of the translational and rotational dynamics which generates an almost perpendicular crossing of the D-trans and D-rot isodiffusivity lines. While the self-intermediate scattering function exhibits stretched relaxation, i.e., glassy dynamics, only for large phi and X-0 approximate to 1, the second order orientational correlator C-2(t) shows stretching only for large and small X-0 values. We discuss these findings in the context of a possible prenematic order driven glass transition.
Iris type:
01.01 Articolo in rivista
Keywords:
GLASS-TRANSITION; LIQUIDS; PHASE; SIMULATIONS; PARTICLES
List of contributors:
Sciortino, Francesco
Handle:
https://iris.cnr.it/handle/20.500.14243/165802
Published in:
PHYSICAL REVIEW LETTERS (PRINT)
Journal
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