Metallic glass-formers in 2D exhibit the same scaling as in 3D between vibrational dynamics and structural relaxation
Articolo
Data di Pubblicazione:
2020
Abstract:
Glass-forming systems approaching their glass transition exhibit universal correlations between picosecond vibrational dynamics and long-time structural relaxation, which can be described by the same master curve in the bulk or confined conditions. In this work, we study at a fundamental level the effects of the reduction of spatial dimensionality on this phenomenon. We perform molecular dynamics simulations of a metallic glass-formers in two dimensions (2D). We show that in the supercooled regime particle localization in the cage and structural relaxation are blurred by long-wavelength fluctuations specific to low-dimensional systems. Once these effects are properly removed, we demonstrate that the fast dynamics and slow relaxation comply, without any adjustment, with same scaling between the structural relaxation time and the Debye?Waller factor, originally observed in three-dimensions (3D).
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
supercooled liquids; 2D systems; metallic glasses; vibrational dynamics; structural relaxation; molecular dynamics simulations
Elenco autori:
Leporini, Dino; Massa, CARLO ANDREA
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