A New Chiral Tridentate Ferrocenyl Ligand. Synthesis and Characterization of Its Palladium(I1) and Nickel(I1) Complexes
Academic Article
Publication Date:
1995
abstract:
A novel chiral tridentate phosphine ligand
based on ferrocene (5) can be readily obtained from
cyclohexylphosphine and N,N-dimethyl-(S)-l-[(R)-2-
(diphenylphosphino)ferrocenyllethylamine (4) in acetic
acid. Ligand 5 adopts a meridional coordination geometry
with d8-metal centers. The crystal structure of
[Pd(5)ClIPF6 (6) has been determined.
Iris type:
01.01 Articolo in rivista
List of contributors:
Barbaro, Pierluigi
Published in: