A New Chiral Tridentate Ferrocenyl Ligand. Synthesis and Characterization of Its Palladium(I1) and Nickel(I1) Complexes
Articolo
Data di Pubblicazione:
1995
Abstract:
A novel chiral tridentate phosphine ligand
based on ferrocene (5) can be readily obtained from
cyclohexylphosphine and N,N-dimethyl-(S)-l-[(R)-2-
(diphenylphosphino)ferrocenyllethylamine (4) in acetic
acid. Ligand 5 adopts a meridional coordination geometry
with d8-metal centers. The crystal structure of
[Pd(5)ClIPF6 (6) has been determined.
Tipologia CRIS:
01.01 Articolo in rivista
Elenco autori:
Barbaro, Pierluigi
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