Validity of the Franck-Condon principle in the optical spectroscopy: Optical conductivity of the Frohlich polaron
Articolo
Data di Pubblicazione:
2006
Abstract:
The optical absorption of the Frohlich polaron model is obtained by an approximation-free diagrammatic Monte Carlo method and compared with two new approximate approaches that treat lattice relaxation effects in different ways. We show that: (i) a strong coupling expansion, based on the Franck-Condon principle, well describes the optical conductivity for large coupling strengths (alpha > 10); (ii) a memory function formalism with phonon broadened levels reproduces the optical response for weak coupling strengths (alpha < 6) taking the dynamic lattice relaxation into account. In the coupling regime 6
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
INTERMEDIATE-VALENCE; SLOW ELECTRONS; GROUND-STATE; ABSORPTION; CRYSTAL
Elenco autori:
DE FILIPPIS, Giulio
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