Chemically Directed Assembling of Functionalized Luminescent Nanocrystals onto Plasma Modified Substrates Towards Sensing and Optoelectronic Applications

In this work semiconductor nanocrystals (NCs) were assembled by means of a layer-by-layer procedure, by properly combining RF (13.56 MHz) glow discharge-assisted processes with wet chemistry approaches. Colloidal core shell type NCs formed by CdSe coated with an epitaxial layer of ZnS (CdSe@ZnS) were then assembled, from aqueous solution, onto the plasma modified materials. The obtained results show that spatially resolved NC assembling can be successfully achieved on micro-structured domains obtained by means of plasma assisted processes. Layers of functionalized NCs are thus demonstrated to be materials that can be effectively integrated into devices for application in photovoltaics, electronic nano-devices and biological sensors.