Data di Pubblicazione:
2005
Abstract:
We examine the vitrification and melting of asymmetric star polymer mixtures by combining rheological measurements with mode coupling theory. We identify two types of glassy states, a single glass, in which the small component is fluid in the glassy matrix of the big one, and a double glass, in which both components are vitrified. Addition of small-star polymers leads to melting of both glasses, and the melting curve has a nonmonotonic dependence on the star-star size ratio. The phenomenon opens new ways for externally steering the rheological behavior of soft matter systems.
Tipologia CRIS:
01.01 Articolo in rivista
Elenco autori:
Sciortino, Francesco; Zaccarelli, Emanuela
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