A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine

Articolo
Data di Pubblicazione:
2013
Abstract:
Treatment of 2-diphenylphosphino-6-methylpyridine (dpPyMe) with Cu(CH3CN)(4)BF4 afforded the stable dinuclear Cu(I) complex [Cu-2(mu-dpPyMe)(3)(CH3CN)](BF4)(2). This compound is a weak emitter in solution, however a remarkably high emission quantum yield (46%) has been found in a rigid matrix at room temperature.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
RAY CRYSTAL-STRUCTURE; BINUCLEAR COPPER(I); ASYMMETRIC CATALYSIS; LIGANDS
Elenco autori:
Autori di Ateneo:
Link alla scheda completa:
https://iris.cnr.it/handle/20.500.14243/262324
Pubblicato in:
CHEMICAL COMMUNICATIONS (LOND., 1996, PRINT)
Journal