ORGANOMETALLICS

Rivista

Codice:

E126469

ISSN:

0276-7333

Dati Generali

Pubblicazioni (191)

1,3-Diphenylallyl Complexes of Pd(II). NMR, X-ray and Catalytic Studies

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2H NMR investigation of the rhodium-catalyzed deuterioformylation of 1,1-diphenylethene: evidence for the formation of a tertiary alkyl-metal intermediate

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A New Chiral Tridentate Ferrocenyl Ligand. Synthesis and Characterization of Its Palladium(I1) and Nickel(I1) Complexes

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A New Way to both Oligothiophene-Spaced Bimetallic Complexes and Functionalized Oligothiophenes

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A Novel Diruthenium Acetylide Donor Complex as an Unusual Active Material for Bulk Heterojunction Solar Cells

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A Theoretical Analysis of Bonding and Stereochemical Trends in Doubly Bridged Cu(I)-Cu(I) Dimers

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A dynamic density functional study of the stepwise migratory insertion of isocyanides into zirconium-carbon bonds anchored to a calix[4]arene moiety

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A simple route to novel palladium(II) catalysts with oxazolin-2-ylidene ligands

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Addition of E-H Bonds (E = S, N) across the Ca=Cb Bond of the Allenylidene Ligand in [Re{C=C=CPh2}(CO)2(triphos)](OSO2CF3) [triphos = MeC(CH2PPh2)3]

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Allenylidene to Indenylidene Rearrangement in Cationic p-Cymene Ruthenium(II) Complexes: Solvent, Counteranion and Substituent Effects in the Key Step Toward Catalytic Olefin Metathesis

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Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance

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Application of Chiral Amine-Imine Ligands in Palladium-Catallyzed Polyketone Synthesis: Effect of Ligand Backbone on the Polymer Stereochemistry

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Assembling ethylene, alkyl, hydride, and carbon monoxide ligands at iridium

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Asymmetric Hydroformylation of Olefins with Rh Catalysts Modified with Chiral Phosphine-Phosphite Ligands

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Bent metallocenes containing ancillary ligands in ring-bridging chains. Synthesis, spectroscopy, and X-ray crystal structure of [2,6-pyridinediylbis(methylcyclopentadienyl)]chromium(II)

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Benzene Hydrogenation by Silica-Supported Catalysts Made of Palladium Nanoparticles and Electrostatically Immobilized Rhodium Single Sites

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Bidentate NHC-Cobalt Catalysts for the Hydrogenation of Hindered Alkenes

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Bimetallic Aluminum Complexes Bearing Binaphthyl-Based Iminophenolate Ligands as Catalysts for the Synthesis of Polyesters

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Bis(Pentafluorophenyl)Borinic Acid: A Cyclic Trimer in the Solid State and a Monomer, with Hindered Rotation around the B-OH Bond, in Solution

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Blue Phosphorescence of Trifluoromethyl- and Trifluoromethoxy-Substituted Cationic Iridium(III) Isocyanide Complexes

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Bond Activation by Electron Transfer in Indenyl Ru (II) Complexes. The Electrochemical Reduction of [Ru(h5-C9H7)Cl(L)2] and [Ru(h5-C9H7)(L)2]+, L2 = COD, L = PPh3

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Boron Functionalization and Unusual B-C Bond Activation in Rhodium(III) and Iridium(III) Complexes with Diphenylbis(pyrazolylborate) Ligands (Ph2Bp)

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C-S cleavage of benzo[b]thiophene at ruthenium

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Cationic carboxylato complexes of dirhodium(II) with oxo-thioethers: promising catalysts with unusual coordination modes

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Characterization and Reactivity of the Tetrametallic Pd2-Mo2 Complex Ph(Bu)P( Ø5-C5H4)Mo(CO)3Pd( Ý-I)2PdMo(CO)3( Ø5-C5H4)P(Ph)Bu and its Use to Model Pd-Catalyzed Cross-Coupling Reactions Leading to M-C kC Bonds

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Characterization and Reactivity of the Tetrametallic Pd2-Mo2 Complex Ph(Bu)P(h5-C5H4)Mo(CO)3Pd(m-I)2PdMo(CO)3(h5-C5H4)P(Ph)Bu and Its Use to Model Pd-Catalyzed Cross-Coupling Reactions Leading to M¾CºC Bonds

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Charge Transfer Properties in Cyclopenta[/]phenanthrene Ferrocenyl Complexes

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Charge Transfer Properties of Benzo[b]thiophene Ferrocenyl Complexes

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Charge Transfer through Isomeric Unsaturated Hydrocarbons. Redox Switchable Optical Properties and Electronic Structure of Substituted Indenes with a Pendant Ferrocenyl

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Chemical and Electrochemical Redox Behavior of 9-Anthrylmethyl-Functionalized h 5 -Cyclopentadienyl Derivatives of Rhodium(I) and Iridium(I): Generation and EPR Characterization of the Corresponding Cation Radicals

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Chemical and thermal behavior of the molecular models [Os-3(CO)(10)(mu-H)(mu-OSiR2R `)] (R = Et, Ph; R ` = Et, Ph, OH, OSiPh2OH): Molecular approach to the clarification of the surface chemistry of the silica-anchored cluster [Os-3(CO)(10)(mu-H)(mu-OSi )]

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Chiral P,S-Ligands Based on ?-d-Thioglucose Tetraacetate. Palladium(II) Complexes and Allylic Alkylation

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Comparative DFT analysis of ligand and solvent effects on the mechanism of H2 activation in water mediated by half-sandwich complexes [Cp Ru(PTA)2Cl] (Cp = C5H5, C5Me5; PTA = 1,3,5-triaza-7-phosphaadamantane)

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Concerted Electron Transfer in Iminopyridine Chromium Complexes: Ligand Effects on the Polymerization of Various (Di)olefins

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Conformationally Constrained Diphosphine Derived from (h6-(S)-N,N-dimethyl-1-aminoindane)Cr(CO)3: Synthesis and Application in Enantioselective Hydrogenation

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Crystal Structure of the Organometallic Polymer [Pd{CH2C(O)Me}Cl]n, Determined by X-ray Powder Diffraction Methods

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Cyclization of 2-Alkynyldimethylaniline on Gold(I) Cationic and Neutral Complexes

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Cyclometalated 4-Styryl-2-phenylpyridine Platinum(II) Acetylacetonate Complexes as Second-Order NLO Building Blocks for SHG Active Polymeric Films

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DFT Investigation of Ligand-Based Reduction of CO2 to CO on an Anionic Niobium Nitride Complex: Reaction Mechanism and Role of the Na+ Counterion

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Density Functional Study of Alkyne to Vinylidene Rearrangements in [(Cp)(PMe3)2Ru(HCCR)]+ (R = H, Me)

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Density Functional Study of CO Insertion into the Metal-Alkyl Bond in Bis(cyclopentadienyl)-Zr-(CH3)2

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Density Functional Study of CO Insertion into the Metal-Alkyl Bond in Bis(cyclopentadienyl)-Zr-(CH3)2

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Density Functional Study of Carbon-Carbon Bond Activation in Curved Polyaromatic Hydrocarbons by Transition-Metal Complexes

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Density Functional Study of the Reppe Carbonylation of Acetylene

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Designing molecules for metal-metal electronic communication: synthesis and molecular structure of the couple of heterobimetallic isomers eta6-(2-ferrocenyl) indene]-Cr(CO)3 and eta6-(3-ferrocenyl)indene]-Cr(CO)3

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Dialkyl effect on enantioselectivity: pi-stacking as a structural feature in P,N complexes of palladium(II)

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Diastereoselective Synthesis of the Indenylruthenium(II) Complexes [Ru(n5-C9H7){k3(P,C,C)-Ph2P(CH2CR=CH2))(PPh3)][PF6](R = H, Me): Enantiofacial Coordination, Hemilabile Properties, and Diastereoselective Nucelophilic Additions to k3 (P,C,C)-Allylphosphin

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Dinuclear N-Heterocyclic Dicarbene Gold Complexes in I-III and III-III Oxidation States: Synthesis and Structural Analysis

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Disubstituted Ferrocenyl Iodo- and Chalcogeno-Alkynes as Chiral Halogen and Chalcogen Bond Donors

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Donor Properties of Diphosphine Ligands in Tungsten Carbonyl Complexes: Synchrotron Radiation XPS Measurements and DFT Calculations

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Dynamical Density Functional Study of Acetylene to Vinylidene Isomerization in (Cp)(CO)2Mn(HCCH)

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Dynamical Density Functional Study of the Multistep CO Insertion into Zirconium-Carbon Bonds Anchored to a Calix[4]arene Moiety

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EXAFS, DFT, Light-Induced Nucleobase Binding, and Cytotoxicity of the Photoactive Complex cis-[Ru(bpy)(2)(CO)Cl](+)

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Effect of Quaternary Phosphonium Salts as Cocatalysts on Epoxide/CO2 Copolymerization Catalyzed by salen-Type Cr(III) Complexes

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Effect of the Coordination to M(II) Metal Centers (M = Zn, Cd, Pt) on the Quadratic Hyperpolarizability of Various Substituted 5-X-1, 10-phenanthrolines (X = Donor Group) and of trans-4-(Dimethylamino)-4'-stilbazole

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Effect of the Coordination to the "Os3(CO)11" Cluster Core on the Quadratic Hyperpolarizability of trans-4-(4'-X-styryl)pyridines (X = NMe2, t-Bu, CF3) and trans,trans-4-(4'-NMe2-phenyl-1,3-butadienyl)pyridine

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Effect of the coordination to M(II) metal centers (M = Zn, Cd, Pt) on the quadratic hyperpolarizability of various substituted 5-X-1,10-phenanthrolines (X = donor group) and of trans-4-(dimethylamino)-4 `-stilbazole

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Electron transfer catalysis in the activation of C-H bonds by iridium complexes

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Electronic communication in homobimetallic anthracene-bridged ·5-cyclopentadienyl derivatives of rhodium(I): generation and characterization of the cation-radicals species [L2Rh{C5H4CH2(9,10-anthrylene)CH2C5H4}RhL2]+.

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Electronic effect of diphosphines on the regioselectivity of the palladium-catalyzed hydroesterification of styrene

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Electronically and sterically induced structural distortions in square-planar d(8) complexes

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Enantioselective Hydrogenation of 2-Methylquinoxaline to (-)-(2S)-2-Methyl-1,2,3,4-tetrahydroquinoxaline by Iridium Catalysis

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Enantioselective palladium-catalyzed hydrosilylation of styrene: Detailed reaction mechanism from first-principles and hybrid QM/MM molecular dynamics simulations

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Enantioselective palladium-catalyzed hydrosilylation of styrene: Influence of electronic and steric effects on enantioselectivity and catalyst design via hybrid QM/MM molecular dynamics simulations

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Ethylene Carbonylation in Methanol and in Aqueous Media by Palladium(II) Catalysts Modified with 1,1 -Bis(dialkylphosphino)ferrocenes

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Exploring the anticancer potential of diiron bis-cyclopentadienyl complexes with bridging hydrocarbyl ligands: Behavior in aqueous media and in vitro cytotoxicity

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Extensive Experimental and Computational Study of Counterion Effect in the Reaction Mechanism of NHC-Gold(I)-Catalyzed Alkoxylation of Alkynes

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Extreme Tuning of Redox and Optical Properties of Cationic Cyclometalated Iridium(III) Isocyanide Complexes

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Four- and Five-Coordinate CO Insertion in the Copolymerization of Carbon Monoxide and Olefins Catalyzed by Diphosphine Nickel(II) Complexes: A Dynamical Density Functional Study

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Full Quantum Mechanical Investigation of the Unimolecular versus Bimolecular Acetylene to Vinylidene Rearrangement in the Prototype trans-Cl-Rh(Pi-Pr3)2 Complex

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Functionalized Ruthenium Dialkynyl Complexes with High Second-Order Nonlinear Optical Properties and Good Potential as Dye Sensitizers for Solar Cells

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Group 10 metal complexes with chelating macrocyclic dicarbene ligands bearing a 2,6-lutidinyl bridge: Synthesis, reactivity, and catalytic activity

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Heterobimetallic (ferrocenyl)indenyl rhodium complexes. Synthesis, crystal structure, and oxidative activation of [eta(5)-(1-ferrocenyl)indenyl]RhL2 [L-2 = COD, NBD, (CO)(2)]

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Heterobimetallic Iron-Rhodium Complexes. Synthesis and Characteristics of CpFe(mu-eta5:eta5-as-indacenediide)RhL2 (L2 = COD, NBD, (ethylene)2)

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Heterobimetallic Iron-Rhodium Complexes. The Synthesis and Characteristics of CpFe-(?Ý-?Ø5:?Ø5-as-Indacene-diide)-RhL2 [L2= COD, NBD, (Ethylene)2]

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Homo- and Co-Polymerization of Ethylene with Cyclic Olefins Catalyzed by Phosphine Adducts of (Imido)vanadium(IV) Complexes

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Homogeneous Hydrogenation of Benzo[b]thiophene by Use of Rhodium and Iridium Complexes as the Catalyst Precursors: Kinetic and Mechanistic Aspects

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Hydrogen Transfer Activation via Stabilization of Coordinatively Vacant Sites: Tuning Long-Range pi-System Electronic Interaction between Ru(0) and NHC Pendants

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Hydrogen-Bond-Assisted, Concentration-Dependent Molecular Dimerization of Ferrocenyl Hydantoins

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Hydrogenation of Indole by Phosphine-Modified Rhodium and Ruthenium Catalysts

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Hydrosilylation Reactions of C-C Multiple Bonds in Water. Comparative Study of the Radical Initiation Mechanisms

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Imidazolyl PTA Derivatives as Water Soluble (P,N) Ligands for Ru-catalysed Hydrogenations

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Imine Hydrogenation by Tribenzylphosphine Rhodium and Iridium Complexes

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In Situ High-Pressure 31P{1H} NMR Studies of the Hydroformylation of 1-Hexene by RhH(CO)(PPh3)3

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In Situ and Reactor Study of the Enantioselective Hydrogenation of Acetylacetone by Ruthenium Catalysis with the New Chiral Diphosphine Ligand (R)-(R)-3-Benzyl-2,4-bis(diphenylphosphino)pentane

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Insertion Reactions of Alkynes into the Ru-H Bond of Indenylruthenium(II) Hydride Complexes. Mechanism of the Reaction of Phenylacetylene with [RuH(C9H7)(dppm)] (dppm ) Bis(diphenylphosphino)methane)

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Inter- and Intra-Molecular Protium-Deuterium Exchange in the Rhodium-Catalyzed Deuterioformylation of Styrene

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Intermolecular Complexes as Reactive Species in the Migratory CO Insertion of Indenyliron(II) Alkyl Complexes

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Intervalence Charge Transfer in Heterotrinuclear Fe-Rh-Cr Triads of the Polyaromatic Cyclopentadienyl-Indenyl Ligand

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Intramolecular coupling of eta2-Iminoacyls on Zr-di-aryloxides and -calix[4]arenes: A revised mechanism by DFT calculations and Car-Parrinello molecular dynamics simulations

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Introducing a New Family of Biotinylated Ir(III)-Pyridyltriazole Lumophores: Synthesis, Photophysics, and Preliminary Study of Avidin-Binding Properties

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Iridium(I) Complexes of Upper Rim Functionalized PTA Derivatives. Synthesis, Characterization and Use in Catalytic Hydrogenations (PTA = 1,3,5-triaza-7-phosphaadamantane)

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Kinetic Evidence of an Arm-Off Mechanism in Complexes of Hemilabile Hybrid Ligands-Oxidative Additino of Methyl Iodide to the Rhodium(I) Complex [Rh(2,6-bis(Benzylthiomethyl)pyridine)(CO)]PF6 via Competitive Pathways

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Kinetic and Product Studies of the Reaction of Triorganosilanes with Dimethyldioxirane

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Ligand Effects on the Rates of the Migratory Insertion in Rhodium(III) Methyl Carbonyl Complexes

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Ligand and solvent effect in the alternating copolimerization of carbon monoxide and olefins by palladium- diphosphine catalysis

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Low-Temperature Nucleophilic Attack of Me3SiO- and MeO- on Rhenium(I) and Rhenium(0) Carbonyl Complexes

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Luminescent Conjugates between Dinuclear Rhenium Complexes and Peptide Nucleic Acids (PNA): Synthesis, Photophysical Characterization, and Cell Uptake

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Mechanism of photodegradation of polysilanes: A relaxed cross section of the conical intersection hyperline in 2-methyltrisilane

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Metalation of Alkynes. 3. Kinetics of Acetoxythallation

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Metalation of Alkynes. 5. Reaction of Diphenylethyne with Mercuric Salts in Alcohols. Synthesis, Stereochemistry and Structure of (beta-Alkoxyvinyl)mercury Adducts

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Methoxycarbonylation of Ethene by Palladium(II) Complexes with 1,1'-Bis(diphenylphosphino)octamethylferrocene (dppomf)

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Mimicking the HDS activity of ruthenium-based catalysts. Homogeneous hydrogenolysis of benzo[b]thiophene

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Mixed Valence Properties in Ferrocenyl-Based Bimetallic FeCp-Indenyl-MLn Complexes: Effect of the MLn Group

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NHC-Gold-Alkyne Complexes: Influence of the Carbene Backbone on the Ion Pair Structure

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New chromium (II) bidentate phosphine complexes: synthesis, characterization, and behavior in the polymerization of 1,3-butadiene

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New eta(2)-formamidiny zirconium complexes: Synthesis, characterization, and catalytic activity

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New water-soluble ruthenium(II) and osmium(II) hydroxo carbonyl complexes

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Novel Fullerene Platinum Alkynyl Complexes with High Second Order Nonlinear Optical Properties as a Springboard for NLO-Active Polymer Films

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Novel high-yield method for the synthesis of [Os-3(CO)(10)(mu-H)(mu-OSiR2R `)] species and X-ray characterization of [Os-3(CO)(10)(mu-H)(mu-OSiPh2OSiPh2OH)] and [Os-3(CO)(10)(mu-H)(mu-OSiPh2OH)], first molecular models of osmium surface species anchored to vicinal and geminal surface silanols

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Olefin Insertion into the Rhodium-Hydrogen Bond as the Step Determining the Regioselectivity of Rhodium-Catalyzed Hydroformylation of Vinyl Substrates: Comparison between Theoretical and Experimental Results

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Operando High-Pressure NMR and IR Study of the Hydroformylation of 1-Hexene by 1,1'-Bis-(Diarylphosphino)metallocene-Modified Rhodium(I) Catalysts

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Opposite chemoselectivity (hydrogenation versus carbonylation) shown by 4-vinylpyridine with respect to 3-vinylpyridine under hydroformylation conditions with Rh4(CO)12

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Organo-f-element thermochemistry. Actinide-group 14 element and actinide-transition-element bond disruption enthalpies and stoichiometric/catalytic chemical implications thereof in heterobimetallic tris(cyclopentadienyl)uranium(IV) compounds

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Organometallic chemistry of Ph3PC=C=O. Synthesis, characterization, X-ray structure determination, and density functional study of the first stable bis-eta(1)-ketenyl complex, trans-[PtCL2{eta(1)-C(PPh3)CO}(2)]

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Origin of the Deactivation in Styrene Aziridination by Aryl Azides, Catalyzed by Ruthenium Porphyrin Complexes. Structural Characterization of a Ë2-1,2,3-Triazoline RuII(TPP)CO Complex

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Oxidation of thiophene derivatives with H2O2 in acetonitrile catalyzed by [Cp*2M2O5] (M = Mo, W): a kinetic study

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Oxidative Addition of Methyl Iodide and CO Migratory Insertion in a Cationic Rhodium Complex of a S,N,S Tridentate Ligand

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PGSE NMR studies on RAPTA derivatives: evidence for the formation of H-bonded dicationic species

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Palladium(II) Complexes with 1,1'-Bis(diphenylphosphino)ferrocenes [Fe(hapto5-C5R4PPh2)2]n+ (dppf, R= Me, n=0; dppomf, R= Me, n=0; dppomf+, R= Me, n=1). Synthesis, Characterization, and Catalytic Activity in Ethene Methoxycarbonylation

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Palladium(II) Complexes with N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Coordination Chemistry and Catalysis

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Palladium(II)-Catalyzed Rearrangement and Oligomerization Reactions of cis-Bicyclo[4.2.0]oct-7-ene

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Pd nanoparticle catalyzed heck arylation of 1,1-disubstituted alkenes in ionic liquid. Study on factors affecting the regioselectivity of the coupling process

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Phosphine Substitution in Indenyl- and Cyclopentadienylruthenium Complexes. Effect of the eta5 Ligand in a Dissociative Pathway

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Preparation, Characterization, and Performance of the Supported Hydrogen-Bonded Ruthenium Catalyst [(sulphos)Ru(NCMe)3](OSO2CF3)/SiO2. Comparisons with Analogous Homogeneous and Aqueous-Biphase Catalytic Systems in the Hydrogenation of Benzylideneacetone and Benzonitrile

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Pyrazole-Based PCN Pincer Complexes of Palladium(II): Mono- and Dinuclear Hydroxide Complexes and Ligand Rollover C-H Activation

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Quantifying steric effects of a-diimine ligands. Oxidative addition of MeI to Rh(I) and migratory insertion in Rh(III) complexes

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REACTION OF FISCHER TYPE CHROMIUM CARBENE COMPLEXES WITH N,N-DIMETHYLFORMAMIDE DIALKYL ACETALS (DMF-DAA) - AN UNEXPECTED CARBON-CARBON BOND BREAKING

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Rate Studies and Mechanism of Ring-Closing Olefin Metathesis Catalyzed by Cationic Ruthenium Allenylidene Arene Complexes

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Rate Studies on the Release of Terminal Alkynes from Indenylruthenium(II) Vinylidene Complexes. Implications on the Mechanism of eta-1-Vinylidene into eta-2-Alkyne Isomerization

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Reaction of Ethynylferrocene with Mercuric Acetate

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Reaction of cyclopentadienyl ruthenium complexes with a carborane anion: effect of the spectator ligands on the substitution site

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Reactivity of Rhenium Allenylidenes towards phosphines: a theoretical study

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Reactivity of [TpRuCl(PTA)(PPh3)] with Alkynes and Propargylic Alcohols: The Occurrence of Structurally Related Cationic vs Neutral Allenylidene Complexes with the Hydrido tris(pyrazolylborate) Ruthenium Moiety

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Regio- and diastereoselective nucleophilic additions of lithium enolates on the allenylidene complexes [Ru{= C = C = C(R)Ph}(eta(5)-C9H7)(PPh3)2][PF6] (R = H, Ph): Synthesis of the first chiral keto-functionalized (sigma-alkynyl)ruthenium(II) complexes

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Regioselective Hydromethoxycarbonylation of Terminal Alkynes Catalyzed by Palladium(II)-Tetraphos Complexes

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Reversible Reductive Dimerization of Diiron m-Vinyl Complex via C-C Coupling: Characterization and Reactivity of the Intermediate Radical Species

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Reversible gas-solid reactions between the organometallic zwitterion [(eta(5)-C5H4COOH)(eta(5)-C5H4COO)Co-III] and vapors of trifluoroacetic and tetrafluoroboric acids

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Rhodium-Mediated Functionalization of White Phosphorus: A Novel Formation of C-P Bonds

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Rhodium-catalyzed hydroformylation of 4-vinylpyridine: 4-ethylpyridine formation via an unusual cleavage of the Rh-C bond by the enolic form of the oxo product

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Rhodium-catalyzed hydrofrmylation of 4-vinylpyridine: 4-ethylpyridine formation via an unusual cleavage of the Rh-C bond by the enolic form of the oxo product

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Ruthenium Promoted Z-Selective Head-to-Head Dimerization of Terminal Alkynes in Organic and Aqueous Medium

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Ruthenium(II) pi greco-alkyne and vinylidene complexes derived from glycoynitols: new precursors for water soluble unsaturated carbenes

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Selective Ethylene Dimerization by Palladium(II) Complexes Bearing a Phosphinoferrocene Sulfonate Ligand

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Selective Oligomerization of Ethylene to Linear a-Olefins by Tetrahedral Cobalt(II) Complexes with 6-(Organyl)-2-(imino)pyridyl Ligands: Influence of the Heteroatom in the Organyl Group on the Catalytic Activity

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Single Two-Electron Transfers and Successive One-Electron Transfers in Biferrocenyl-Indacene Isomers

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Single-Step Synthesis of Dinuclear Neutral Gold(I) Complexes with Bridging Di(N-heterocyclic carbene) Ligands and Their Catalytic Performance in Cross Coupling Reactions and Alkyne Hydroamination

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Strong Electron-Donating Ligands Accelerate the Protodeauration Step in Gold(I)-Catalyzed Reactions: A Quantitative Understanding of the Ligand Effect

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Structural and Electronic Rearrangements upon the Oxidation of Binuclear (Ru2) and Trinuclear (MoRu2) Complexes with Bridging o-Phenylenediamido Ligands

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Structures and energetics of axial and equatorial 1-methyl-1-silacyclohexane

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Studies of Ligand and Solvent Effects in the Alternating Copolymerization of Carbon Monoxide and Ethene by Palladium-Diphosphine Catalysis

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Study of the Electronic Structure of M-2(CH2CMe3)(6) (M = Mo, W) by Photoelectron Spectroscopy and Density Functional Theory

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Styrene Cyclopropanation and Ethyl Diazoacetate Dimerization Catalyzed by Ruthenium Complexes Containing Chiral Tridentate Phosphine Ligands

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Surface Organometallic Chemistry: Synthesis and X-Ray Characterization of Novel Silanolate Surface Models [Re2(CO)8(mu-H)(mu-OSiR2r?)] and of the First Models with two Homo and Hetero Metalcarbonyl Fragments Linked to Vicinal or Geminal Silanols

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Surface-mediated organometallic synthesis: High-yield and selective syntheses of neutral and anionic ruthenium carbonyl clusters by controlled reduction of silica-supported RuCl3 in the presence of Na2CO3 or K2CO3

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Surface-mediated organometallic synthesis: The activating role of silica for a high-yield route to [H4Os4(CO)(12)] and [HOs3(CO)(10)Y] (Y = OH, OR, Cl, Br, I, O2CR, SCN) clusters from [Os-3(CO)(12)]

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Synthesis and Catalytic Activity of Titanium Silsesquioxane Frameworks as Models of Titanium Active Surface Sites of Controlled Nuclearity

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Synthesis and Characterization of Osmium-Containing Silsesquioxanes: High-Yield Routes to {Os3(CO)10(mu-H)[(mu-O)Si7O10(c-C6H11)7]} and the New Clusters {Os3(CO)10(mu-H)[(mu-O)Si7O9(OH)2(c-C6H11)7]}, {[Os3(CO)10(mu-H)]2(mu-O)2Si7O9(OH)(c-C6H11)7}, {Os3(CO)10(mu-H)[(mu-O)Si8O11(OH)(c-C6H11)8]}, and {[Os3(CO)10(mu-H)]2(mu-O)2Si8O11(c-C6H11)8}

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Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)-P3 or -P2S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone

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Synthesis and Characterization of Trimetallic Complexes Containing M-Pd-M Arrays (M=Mo, W) and their Relevance in Palladium-Catalyzed Metal-Carbon Bond-Formation

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Synthesis and Properties of the Indenyl Ruthenium(II) Complex [Ru{(E)-.eta.1-C(CCPh):CHPh}(.eta.5-C9H7)(.kappa.2-P-dppm)] (dppm = bis(diphenylphosphino)methane). An Organometallic Intermediate in the Catalytic Dimerization of Phenylacetylene.

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Synthesis and Properties of the Indenyl Ruthenium(II) Complex [Ru{(E)-h1-C(C*cph)=chph}(h5-C9H7)(k2-P dppm)] (dppm= bis(diphenylphosphino)methane). An Organometallic Intermediate in the Catalytic Dimerization of Phenylacetylene

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Synthesis and Reactivity of Indenyl Ruthenium Complexes with the Labile Ligand 1,5-Cyclooctadiene: Catalytic Activity of [Ru(C9H7)Cl(COD)]

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Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane

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Synthesis and molecular structure of the trinuclear mixed-metal complex [{(Me2NCH2CH2CH2) 2Cr(?-Cl)2}2Mg] and of the tetranuclear Grignard reagent [(Me2NCH2CH2CH2)Mg 2Cl3(THF)2]2

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Synthesis and structural investigations of novel palladium(II) and rhodium(I) complexes containing chiral ligands with a stereogenic sulfur donor, such as beta-amino sulfoxides and C-2-symmetric bis-sulfoxides

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Synthesis of Ar-BIAN Ligands (Ar-BIAN = bis(aryl)acenaphthenequinonediimine) Having Strong Electronwithdrawing Substituents on the Aryl Rings and their Relative Coordination Strength towards Pd(0) and Pd(II) Complexes

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Synthesis of New Polydentate Nitrogen Ligands and their Use in Ethylene Polymerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides and Methylaluminoxane

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Synthesis of a New Polydentate Ligand Obtained by Coupling 2,6-Bis(imino)pyridine and (Imino)pyridine Moieties and its Use in Ethylene Oligomerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides

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Synthesis of dendrimers ended by bis(diphenylphosphinomethyl)amino ligands and use of their Palladium complexes for catalyzing C-C cross-coupling reactions

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Synthesis of heterocyclic ligands by diheterocyclization at the rhenium(I) allenylidene [(triphos)(CO)2Re{C=C=CPh2}](OSO2CF3). Part I: Reactivity with dipolar N,N-heterocycles

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Synthesis of polymer-supported rhodium(I)-1,3-bis(diphenylphosphino)propane moieties and their use in the heterogeneous hydrogenation of quinoline and benzylideneacetone

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Synthesis of polymer-supported rhodium(I)-1,3-bis(diphenylphosphino)propane moieties and their use in the heterogeneous hydrogenation of quinoline and benzylideneacetone

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Synthesis, Characterization and Reactivity of 1,1'-Bis(diphenylphosphino)osmocene: Palladium(II) Complexes and Their Use as Catalysts in the Methoxycarbonylation of Olefins

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Synthesis, Solid-State Structure and Solution Behavior of Hydrido-Bridged Adducts between the Group 11 [M(pph3)]+ Cations and the Triangular Cluster Anion [Re3(mu-H)4(CO)9(pph3)]

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Synthesis, Spectroscopic, and X-ray Characterization of Rhenium Carbonyl Complexes with Different Silsesquioxanes, as Models That Mimic the Chemical Behavior and the Topology of the Silica Surface

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Synthesis, characterization and electrochemical behavior of mono- and bimetallic Ru and Re allenylidenes bearing multiconjugated organic spacers

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Taking Too Many Precautions in Making a Catalyst is Never a Loss of Time

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Tetrathia[7]helicene-based complexes of ferrocene and (? 5- cyclohexadienyl)tricarbonylmanganese: Synthesis and electrochemical studies

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The Chemical Bond in Gold(I) Complexes with N-Heterocyclic Carbenes

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The Reaction of the Ruthenium(II) Indenyl Complex [Ru(n5-C9H7)[k3(P,C,C)-PPh2(CH2CH=CH2)](PPh3)][PF6] with Terminal Alkynes. Mechanisms of 1-Alkyne to n1-Vinylidene Transformation and Kinetic Detection of Hemilability of the Allylphosphine Ligand

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The Role of Water in the Oligomerization Equilibria Involving Bis(pentafluorophenyl)borinic Acid in Dichloromethane Solution

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The Unexpected Formation of a Weak Metal-Metal Bond: Synthesis, Electronic Properties and Second Order NLO Responses of Push-Pull Late-Early Heteronuclear Bimetallic Complexes with W(Co)3(1,10-Phenanthroline) Acting as a Donor Ligand

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The role of pi-pi, stacking interactions in square planar palladium complexes. Combined quantum mechanics/molecular mechanics QM/MM studies

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Thermal and Photochemical C-H Bond Activation Reactions at Iridium.- Coordination vs. C-H Cleavage of ethene, Styrene and Phenylacetylene

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Unraveling the Anion/Ligand Interplay in the Reaction Mechanism of Gold(I)-Catalyzed Alkoxylation of Alkynes

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Variable Photon Energy Photoelectron Spectroscopy and Magnetism of YbCp3 and LuCp3

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Vinil Polymerization of Norbornene by Bis(salicylaldiminate)copper(II)/Methylalumoxane Catalist

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Water-assisted H-H bond splitting mediated by [CpRu(PTA)2Cl] (PTA=1,3,5-triaza-7-phosphaadamantane). A DFT analysis.

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X-ray Powder Diffraction Study of Organometallic Polymers: [Ru(L)(CO)2]n (L = 2, 2, '-Bipyridine or 1, 10-Phenanthroline)

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beta-hydride elimination and regioselectivity in the rhodium-catalyzed hydroformylation of open chain unsaturated ethers

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No Results Found