Structural survey of technetium complexes

The review, with 294 references and 41 figures, reports on the main structural features of 240 Tc complexes whose X-ray crystal structure has been determined during the period 1986-1992. It comprises seven major sections: oxo-; nitrido-; diazenido-, hydrazido- and imido-; Schiff base-; chalcogenide-; pnictide-; nitrosyl- and thionitrosyl-technetium complexes. The survey concludes with two comprehensive tables summarizing some properties of Tc complexes vs. oxidation state.