Telomerization of butadiene with methanol catalysed by cationic palladium complexes containing a bidentate phosphinoamino ligand

Academic Article

Publication Date:

1999

abstract:

The cationic complexes [Pd(?q3-allyl){Ph2P(o-C6H4NMe2)}]PF6 (1) and [PdMe(PPh3){Ph2P(o-C6H4NMe2)}]CF3SO3· C6H6 (2) catalyse, without any added phosphine, the telomerization reaction of 1,3-butadiene with methanol, showing high chemio- (> 95%) and regioselectivity towards the linear 1-methoxy-2,7-octadiene (> 93%).

Iris type:

01.01 Articolo in rivista

Keywords:

Telomerization; Phosphinoamines; 1-3 Butadiene; Palladium catalysts; Cationic palladium complexes

List of contributors: