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Ground-state clusters for short-range attractive and long-range repulsive potentials

Academic Article
Publication Date:
2004
abstract:
We report calculations of the ground-state energies and geometries for clusters of different sizes (up to 80 particles), where individual particles interact simultaneously via a short-ranged attractive potential, modeled with a generalization of the Lennard-Jones potential, and a long-ranged repulsive Yukawa potential. We show that for specific choices of the parameters of the repulsive potential, the ground-state energy per particle has a minimum at a finite cluster size. For these values of the parameters in the thermodynamic limit, at low temperatures and small packing fractions, where clustering is favored and cluster-cluster interactions can be neglected, thermodynamically stable cluster phases can be formed. The analysis of the ground-state geometries shows that the spherical shape is marginally stable. In the majority of the studied cases, we find that above a certain size, ground-state clusters preferentially grow almost in one dimension.
Iris type:
01.01 Articolo in rivista
List of contributors:
Zaccarelli, Emanuela
Authors of the University:
ZACCARELLI EMANUELA
Handle:
https://iris.cnr.it/handle/20.500.14243/291754
Published in:
LANGMUIR
Journal
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