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Anomalous melting behavior under extreme conditions: Hard matter turning "soft"

Academic Article
Publication Date:
2008
abstract:
We show that a system of particles interacting through the exp-6 pair potential, commonly used to describe effective interatomic forces under high compression, exhibits anomalous melting features such as reentrant melting and a rich solid polymorphism, including a stable BC8 crystal. We relate this behavior to the crossover, with increasing pressure, between two different regimes of local order that are associated with the two repulsive length scales of the potential. Our results provide a unifying picture for the high-pressure melting anomalies observed in many elements and point out that, under extreme conditions, atomic systems may reveal surprising similarities with soft matter.
Iris type:
01.01 Articolo in rivista
Keywords:
High-pressure phase diagrams of the elements; Liquid-solid transitions; Solid-solid transitions; Reentrant melting
List of contributors:
Saija, Franz
Authors of the University:
SAIJA FRANZ
Handle:
https://iris.cnr.it/handle/20.500.14243/50743
Published in:
THE JOURNAL OF CHEMICAL PHYSICS
Journal
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