Pretreatments for enhanced biomethane production from buckwheat hull: Effects on organic matter degradation and process sustainability

Buckwheat manufacturing produce a large amount of lignocellulosic residue (buckwheat hull), which could be used as substrate in anaerobic digestion, even if hard lignocellulosic structure represents the main obstacle for its degradation. This study presents the results of a laboratory experiment conducted to evaluate the effects of different pretreatments on buckwheat hull anaerobic digestion. To achieve the aim, five pretreatments (alkaline, thermo-alkaline, microwave, ultrasonication and low temperature thermal pretreatment) were studied and the results were compared to non treated buckwheat hull. Cumulative biomethane yields significantly increased after alkaline and thermo-alkaline pretreatments (+61% and +122% with respect to non treated hull, respectively). These results were mainly related to organic matter solubilisation (+772% and +859% of soluble reducing sugars, respectively) and lignin, hemicellulose and cellulose degradation. Overall, process parameters behaviour and digestate quality were not affected by the pretreatments. Alkaline and thermo-alkaline pretreatments were evaluated for their energetic and economic affordability, showing that combination of thermal and alkaline pretreatments ensures significant advantages.