Insights on the electrochemical performance of indirect internal reforming of biogas into a solid oxide fuel cell

The use of biogas in solid oxide fuel cells (SOFCs) is a viable approach for generating power from renewables. However,the direct use of dry biogas in SOFCs causesmany issues concerning the durability of cells. Currently, the conventional approach consists of the use of an external reformer. Nevertheless, other approaches are possible to reduce the complexity of SOFCs.In this paper, we have investigated anindirect internal dry reforming occurring in the anodic chamber of a SOFC as a viable methodto minimise the balance of the plant and simplify the feed management.This approach consisted of coupling a foam coated with NiCo/SDC powder in contact withthe anode of a conventional SOFC cell. The electrochemi-cal experiments demonstrated promising performances at 800 °C byfeeding dry biogas witha maximum power density above 500 mW cm-2 @ 625 mV. The endurance test revealed a stable behaviour over 500 h. Weanalysedthese results according to the physico-chemicalproperties of both catalyst and cell. The combined electrochemical and physico-chemical analyses corroborated the occurrence of multistep reactions in the anodic chamber.