TEMPO-Oxidized Cellulose Cross-Linked with Branched Polyethyleneimine: Nanostructured Adsorbent Sponges for Water Remediation

Adsorbent sponges for water remediation were prepared using TEMPO-oxidized cellulose nanofibers (TOCNFs) as three-dimensional scaffolds, and branched polyethyleneimine (bPEI, 25 KDa) as the cross-linking agent. TOCNFs were suspended in aqueous solution in the presence of variable amounts of bPEI. The mixtures were first freeze-dried and then thermally treated (from 60 to 102 degrees C over 10 h) promoting the formation of amide bonds between the carboxylic groups of TOCNF and the primary amines of bPEI. The resulting materials, which were characterized by FTIR and C-13 CP-MAS NMR spectroscopy, scanning electron microscopy, and elemental analysis, showed higher chemical and mechanical stability in water than non-reticulated cellulose composites. The high adsorption capability of the new sponges was verified for different organic pollutants (p-nitrophenol, 2,4,5-trichlorophenol, and amoxicillin), and heavy metal ion pollutants (Cu, Co, Ni, Cd), indicating their potential for water decontamination.