Spin randomization of light-induced desorbed Rb atoms

We present the first experimental observation of atomic spin randomization of Rb atoms released by light-induced atomic desorption (LIAD). A natural mixture of Rb atoms contained in paraffin and PDMS coated glass cells is irradiated by a free-running diode laser light tuned to the Rb D2 resonance line. The transmission spectrum of the Rb vapor is thus modified and shows a strong enhancement of the hyperfine optical pumping as the light intensity is increased and the laser-frequency scanning rate is decreased. The D2 line spectra are compared for two cases: without and with illumination of the walls of the cell by a UV lamp centered around the wavelength of 404 nm. A simple theoretical model based on the solution of the rate balance equations is introduced in order to analyze the experimental results.