Experimental evidence of biomass burning as a source of atmospheric Cs-137, puy de Dome (1465 m a.s.l.), France.

The presence of cesium-137 (Cs-137) in the environment is mainly due to past nuclear tests and accidental reactor releases. Due to the half-life of Cs-137 (30.2 y), amounts of this radionuclide releases are in fact still detectable in soils, and at trace levels in the vegetation and the atmosphere. Since the middle of the 1990's, the presence of Cs-137 in the atmosphere has long been attributed to the resuspension of terrestrial dust. Recently, modelling studies have demonstrated that an additional and possibly dominant source of this anthropogenic radionuclide is biomass burning. Here, we report the variations of atmospheric Cs-137 activity levels over a 2-year period at the puy de Dome (1465 m a.s.l.), France in combination with measurements of the aerosol chemical composition, in particular with indicators for biomass burning (levoglucosan and potassium) and soil dust (calcium). Temporal co-variations of these chemical compounds in addition to back-trajectories are used to identify common source emissions. Significant correlation is found between these compounds. Hence, we experimentally confirm the modelling study highlighting the fact that the atmospheric Cs-137 is partly released by biomass burning. In addition, we observed that the correlations between the Cs-137 concentrations and levoglucosan and biomass burning K+ differ according to the season. This is in agreement with the temporal evolution of levoglucosan concentration, which has maxima in winter and minima in summer. (C) 2010 Elsevier Ltd. All rights reserved.