Counter cation-controlled air oxidation of manganese derivatives of tetrachlorocatechol

Academic Article
Publication Date:
2000
abstract:
The potassium salt of the triphenylphosphine oxide adduct of bis(tetrachlorocatecholate)mangnnese(III) complex reacts with O-2 in the presence of K+-sequestering agents at room temperature in MeCN resulting in the formation of the corresponding Mn-IV-tris( catecholate) species.
Iris type:
01.01 Articolo in rivista
Keywords:
catecholato complexes; hypervalent compounds; manganese; O-O activation; oxygenation; potassium; VALENCE TAUTOMERISM; GLOBIFORMIS CM-2; COMPLEXES; CATECHOL; SEMIQUINONE; DIOXYGENASE; BENZOQUINONE; CHEMISTRY; LIGANDS; SERIES
List of contributors:
Authors of the University:
Handle:
https://iris.cnr.it/handle/20.500.14243/173255
Published in:
INORGANIC CHEMISTRY COMMUNICATIONS
Journal