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Ring tension, hydrocarbon acidity, and new super-bases

Academic Article
Publication Date:
1986
abstract:
Addn. of di-Na pinacolate or KOCMe3 increased the transmetalating power of pentylsodium in alkane solvents. Some hydrocarbons thus metalated were Me3CCH:CH2, camphene, bicyclo[2.2.2]octene, spiro[4.4]nona-1,3-diene, nortricyclane, norcarane, and housane. Cyclobutanes remained inert.
Iris type:
01.01 Articolo in rivista
Keywords:
Metalation; superbases
List of contributors:
Mordini, Alessandro
Authors of the University:
MORDINI ALESSANDRO
Handle:
https://iris.cnr.it/handle/20.500.14243/213813
Published in:
CHIMIA
Journal
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