Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters

Academic Article
Publication Date:
2002
abstract:
The selectivity of alpha-oxidation of ethers to esters via RuNaOCl can be dramatically improved by pH control, at high substrate to catalyst ratios using a stoichiometric amount of hypochlorite in biphasic media at room temperature.
Iris type:
01.01 Articolo in rivista
Keywords:
ether; oxidation; ruthenium; pH effect; catalysis
List of contributors:
Authors of the University:
Handle:
https://iris.cnr.it/handle/20.500.14243/221797
Published in:
CHEMICAL COMMUNICATIONS (LOND., 1996, PRINT)
Journal