A new platinum vapor-derived highly efficient hydrosilylation catalyst: NMR structural investigation
Articolo
Data di Pubblicazione:
2008
Abstract:
The structural features of a highly efficient hydrosilylation catalyst generated by reaction of Pt vapor and a mixture of mesitylene and 1,3-divinyltetramethyldisiloxane (DVS) were investigated by mono- and bidimensional NMR analyses. The structure around the Pt atoms was highlighted and compared with a commercial sample (Karstedt catalyst) and previously reported Pt vapor-derived system. (C) 2008 Elsevier B.V. All rights reserved.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
platinum; hydrosilylation; NMR; DOSY
Elenco autori:
UCCELLO BARRETTA, Gloria; Mandoli, Alessandro; Evangelisti, Claudio; Vitulli, Giovanni
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