Latent thermal storage for solar cooling applications: materials characterization and numerical optimization of finned storage configurations

The present paper presents the development of a thermal energy storage system for application with non-concentrating solar plants using phase change materials (PCMs). The outcomes of an experimental analysis on commercial and non-commercial PCMs suitable for the desired temperature range is presented, with main focus on to the enthalpy and the cycle stability of the materials. Particularly, a first evaluation of possible degradation mechanisms in hydrated salts was investigated by means of Nuclear Magnetic Resonance (NMR) spectroscopy. The best performing materials have been implemented in a numerical model, based on the enthalpy method, used for the design of a thermal storage system. The configuration of the system, starting from a simple shell-and-tube layout, has been optimised by inserting asymmetric fin-and-tubes and the results with two selected materials have been compared. The analysis has shown that the most promising materials are the commercial ones belonging to the classes of paraffinic materials and hydrated salts and that, with the designed configuration, it is possible to store up to 200 kJ/m3 and get a peak power during discharge of about 1.5 kW.