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Functionalized Ruthenium Dialkynyl Complexes with High Second-Order Nonlinear Optical Properties and Good Potential as Dye Sensitizers for Solar Cells

Academic Article
Publication Date:
2015
abstract:
Various dipolar ?-delocalized Ru(II) dialkynyl complexes were prepared and characterized. Their second-order nonlinear optical (NLO) properties were investigated by the electric-field-induced second harmonic generation (EFISH) technique working in CH2Cl2 solution with an incident wavelength of 1907 nm, whereas the dipole moments were determined by density functional theory (DFT) calculations. All the investigated complexes are characterized by a negative value of ??1.907
Iris type:
01.01 Articolo in rivista
List of contributors:
DE ANGELIS, Filippo
Handle:
https://iris.cnr.it/handle/20.500.14243/282924
Published in:
ORGANOMETALLICS
Journal
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URL

http://dx.doi.org/10.1021/om5009378
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