Novel Fullerene Platinum Alkynyl Complexes with High Second Order Nonlinear Optical Properties as a Springboard for NLO-Active Polymer Films

The synthesis and second-order nonlinear optical (NLO) properties of seven novel fullerene-C-60 derivatives are reported. In these donor bridge acceptor systems, the fullerene unit (acceptor) is connected through a cyclopropane ring to an ethynyl thienyl fragment (bridge) which binds a trimethylsilyl or platinum alkynyl fragment (donor). All derivatives are NLO-active, as determined by the electric field induced second harmonic generation technique, but the fullerene platinum alkynyl complexes are characterized by a particularly large second-order NLO response. Substitution of the thienyl fragment by a terthiophene leads to an increase of the NLO performance by using trimethylsilyl as a donor group, whereas no effect is observed in the case of platinum derivatives. Remarkably, fullerene platinum alkynyl complexes can be dispersed in poly(methyl methacrylate) or polystyrene, affording NLO-active polymer films.