Comprehensive analysis on the effect of lube oil on particle emissions through gas exhaust measurement and chemical characterization of condensed exhaust from a DI SI engine fueled with hydrogen. Part 2: Effect of operating conditions

The need to cope with carbon dioxide abatement has prompted the development of innovative technologies for sustainable mobility. Meanwhile, these technologies consolidate, an important role will be played by internal combustion engines fed with non-fossil fuels such as hydrogen. Theoretically, the combustion of hydrogen should not produce carbon-based emissions. Nevertheless, particles can be found in the exhaust of hydrogen-fueled engines because of the lubricating oil. In this study, a thorough examination of the impact of the engine lubricant on the mechanisms leading to the formation of the particles and the high levels of hazardous pollutants was performed in this study. Experiments were carried out on a direct injection spark ignition engine fueled with hydrogen. The analysis was conducted at 2000 and 3000 rpm both low and full load. Number and size particle distribution were determined by means of on-line measurement on the diluted exhaust. Off-line chemical characterization through analytic techniques was realized on the condensed exhaust and on the particles collected on a filter. Experimental results pointed out that the extent of the particle size varies according to the engine speed and load, evidencing the different role of the oil ascribable to the environmental conditions. It was found that aromatic molecules and nanoparticles are present in the exhausts at all the investigated operating conditions, whereas soot aggregates are formed only at high engine speed.