Effect of Graphite Nanoplatelets Content and Distribution on the Electromagnetic Shielding Attenuation Mechanisms in 2D Nanocomposites

Bidimensional nanomaterials, such as graphene, respond to the rising demand for electromagnetic interference (EMI) shielding materials, followed by the advancements in wireless technology and increased signal sensitivity in electronic devices, especially for the safety of aircraft and other structures. Lightweight nanocomposites reinforced with 2D carbonaceous nanofillers can replace metals thanks to their ability to attenuate electromagnetic waves and low susceptibility to corrosion. In this work, the EMI shielding properties in the X band (8-12 GHz) of high content graphene nanoplatelets (GNPs) nanocomposites have been investigated. Both the effect of filler content and the nanoarchitecture have been studied. For this purpose, two different configurations have been considered, compact and porous, varying the filler content (from 10 wt% to 90 wt%) and the thickness of the samples. Specifically, four different systems have been tested: thin (i) and thick (ii) compact laminates and thin (iii) and thick (iv) porous coatings. The morphology of the material significantly influences its electromagnetic response in terms of reflection and absorption capacity. Maximum effective absorption of 80% was found for disordered structures, while a maximum reflection of about 90% was found for system highly aligned structures.