Bimetallic Activation of White Phosphorus

Academic Article
Publication Date:
2008
abstract:
The formation of novel complexes [M(dppm)(Ph2PCH2PPh2PPPP)]OTf (M = Rh, Ir, dppm = bisdiphenylphoshinomethane, OTf = OSO2CF3) bearing in their coordination sphere a new type of oligophosphorus ligands results from bimetallic activation and consequent transformation of white phosphorus. These complexes display electrophilic properties and can be activated either electrochemically or by interaction with nucleophilic reagents.
Iris type:
01.01 Articolo in rivista
Keywords:
Bimetallic cooperativity; white phosphorus; rhodium and iridium complexes; polyphosphorus ligands
List of contributors:
Authors of the University:
Handle:
https://iris.cnr.it/handle/20.500.14243/158518
Published in:
PHOSPHORUS, SULFUR, AND SILICON AND THE RELATED ELEMENTS
Journal