Spin trapping with phosphonothionesters. Part VI. Phosphoryl- and thiophosphoryl-thionformates
Academic Article
Publication Date:
2001
abstract:
Ethyl (diethoxyphosphoryl)thionformate, ethyl (diethoxythiophosphoryl) thionformate. ethyl (diethoxyphosphoryl)(thiolformate, and ethyl (die thoxythiophosphorl)thiolformate have been allowed to react with a variety of in situ generated free radicals. Spin adducts were observed by EPR with the two thionesters but not with thiolesters even the former compounds, however. exhibited a remarkably lower reactivity than similarly substituted dithioesters.
Iris type:
01.01 Articolo in rivista
Keywords:
FRAGMENTATION CHAIN TRANSFER; OXYGEN-CENTERED RADICALS; TRANSFER RAFT; TERT-BUTYL; IN-VITRO; N-OXIDE; RESONANCE; POLYMERIZATION; THIOKETONES; AGENTS
List of contributors:
Macciantelli, Dante; Alberti, Angelo; Benaglia, Massimo
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