Innovative mesoporous nanosilicas: SBR nanocomposite for low environmental impact tread tyre

Silica nanoparticles with different aspect ratios (A.R.) were tested as reinforcing fillers of styrenebutadiene copolymer (s-SBR) for "green tyres," i.e., tires with lower rolling resistance. A commercial nanosilica with A.R. = 1 (Aerosil® 200) was compared with two nanosilica samples with A.R. = 2 and 4, synthesized by means of an innovative process, to ascertain if the filler shape was significant to improve the composite properties. In addition, bis-triethoxysilylpropyltetrasulfide was grafted onto the particles surface, in order to obtain more hydrophobic materials and to enhance their dispersion in the elastomeric composites: pristine and modified silicas were then compared. Grafting extent was evaluated by thermogravimetric analysis. The surface properties of silicas were investigated by Fourier transform infrared spectroscopy and inverse gas chromatography. s-SBR/silica nanocomposites were then prepared and characterized assessing their dynamic-mechanical properties and carrying out morphological observations by transmission electron microscopy.