Schulz-Flory Oligomerisation of Ethylene by the Dinuclear Nickel(II) Complex Ni2Cl4[cis, trans, cis-tetrakis-(diphenylphosphino)cyclobutane]

Articolo
Data di Pubblicazione:
2003
Abstract:
The binuclear nickel(II) complex Ni2Cl4(cyclo-tetraphos) (cyclo-tetraphos = cis, trans, cis-1,2,3,4-tetrakis-(diphenylphosphino)cyclobutane) forms, upon activation with MAO, an effective and robust catalyst for the oligomerisation of ethylene to Schulz-Flory distributions of C4-C14 olefins with a mechanism where both chain transfer and chain propagation are first order in ethylene.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
nickel; ethylene polymerization; tetraphosphine
Elenco autori:
Autori di Ateneo:
Link alla scheda completa:
https://iris.cnr.it/handle/20.500.14243/170128
Pubblicato in:
DALTON TRANSACTIONS (2003. PRINT)
Journal